December 01, 2015

Chapter 15 - Lecture 8 – Chemical Properties of Alkenes

ACKNOWLEDGEMENT:

Figure
Source of Figure
Figure 13a
http://2012books.lardbucket.org/
Figure 13b
https://www.flickr.com/
Figure 14
https://sites.google.com/site/internationalgcsechemistry/
Figure 15
en.wikibooks.org







Chemical Properties of Alkanes:

Alkenes undergo 3 types of chemical reactions. They are:
  1. Combustion
  2. Addition
  3. Polymerization
Combustion:

Alkenes react with oxygen in the presence of heat, to form carbon dioxide and water.
  
Addition Reaction:

Alkenes have a temporary double bond, which breaks to form different types of compounds, depending on the other reactant present.

Example:

  • Addition reaction of ethene with Bromine:

Ethene reacts with bromine, to form Dibromoethane.
  
This reaction decolourises bromine water and is used as a test for unsaturation.

Figure 13: 


Test for Unsaturation: (L) Before ; (R) After



If an alkane if added to bromine water, no reaction will take place and bromine water would not be decolourised.
  • Addition reaction of ethene with steam:
Ethene reacts with steam, at 300°C temperature and 60 atmosphere pressure, with Phosphoric acid as a catalyst, to form ethanol.


 


Figure 14:



  • Addition reaction of ethene with Hydrogen:
Ethene reacts with hydrogen, in the presence of Palladium or Nickel as a catalyst to yield ethane.
  Figure 15:

This process is knows as hydrogenation of alkenes.


                                                                                       ©Tanzeela Zafar Siddiqui